The innate brittleness of poly has hindered its extensive use in many structural applications. Environment-friendly acids with multifunctional groups, such as 1,2,3,4-butanetetracarboxylic acid, were used to modify PLA chain ends/tails via a melt reaction. At the same time, the strengthened PLA samples preserved the tensile stamina and Young's modulus of neat PLA, suggesting a distinct toughening mechanism that is various from the plasticizing result. To understand the toughening, we recommend a chain end engineering image that can improve the toughness by means of a reduction in the number density of chain defects or finishes of entanglement and the formation of long-branch topological structures.
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CID | MolecularFormula | MolecularWeight | CanonicalSMILES | IsomericSMILES | InChI | InChIKey | IUPACName | XLogP | ExactMass | MonoisotopicMass | TPSA | Complexity | Charge | HBondDonorCount | HBondAcceptorCount | RotatableBondCount | HeavyAtomCount | IsotopeAtomCount | AtomStereoCount | DefinedAtomStereoCount | UndefinedAtomStereoCount | BondStereoCount | DefinedBondStereoCount | UndefinedBondStereoCount | CovalentUnitCount |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
612 | C3H6O3 | 90.08 | CC(C(=O)O)O | CC(C(=O)O)O | InChI=1S/C3H6O3/c1-2(4)3(5)6/h2,4H,1H3,(H,5,6) | JVTAAEKCZFNVCJ-UHFFFAOYSA-N | 2-hydroxypropanoic acid | -0.7 | 90.031694049 | 90.031694049 | 57.5 | 59 | 0 | 2 | 3 | 1 | 6 | 0 | 1 | 0 | 1 | 0 | 0 | 0 | 1 |
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